Hydrothermal Method of Synthesis of β-Ag2MoO4 Nanorods as a Peroxidase Mimetic for Glucose Sensing
Abstract:
In this study, β-Ag₂MoO₄ nanorods were synthesized
using a hydrothermal method, aiming to explore their potential as a sensing
material for L-glucose detection. The synthesis process was optimized to produce
uniform nanorods with high crystallinity and surface area, which is essential
for enhancing sensor performance. The synthesized β-Ag2MoO4 nanorods
characterized by X-ray diffraction (XRD) and scanning electron microscopy
(SEM), confirmed the successful formation of β-Ag₂MoO₄ nanorods with desired
morphological features. The vibrations existing in β-Ag2MoO4 nanorods were
characterized by FT-IR and Raman spectroscopic studies. The electrochemical
properties of the nanorods were evaluated, demonstrating their sensitivity and
selectivity towards L-glucose. The nanorods exhibited a rapid response time,
low detection limit, and excellent reproducibility, making them promising
candidates for glucose sensors. This work underscores the potential of hydrothermally
synthesized β-Ag₂MoO₄ nanorods in the development of advanced glucose sensing
platforms, offering a new approach for the efficient and reliable monitoring of
glucose levels in medical diagnostics.
References:
[1].
Shahsavari,
M., Mortazavi, M., Tajik, S., Sheikhshoaie, I., & Beitollahi, H. 2022,
Synthesis and Characterization of GO/ZIF-67 Nanocomposite: Investigation of
Catalytic Activity for the Determination of Epinine in the Presence of
Dobutamine. Micromachines, 13(1), 88.
[2].
Bharathi, D., Wadaan, M.
A., Mythili, R., & Lee, J. 2024, Synthesis of chitosan and gum arabic
functionalized silver nanocomposite for efficient removal of methylene blue and
antibacterial activity. Polymers for
Advanced Technologies, 35(4),
e6356.
[3].
Arularasu, M. V. 2024,
Biosynthesis, structural characterization and humidity sensing properties of
cellulose/ZnO nanocomposite. Sensing
and Bio-Sensing Research, 45,
100673.
[4].
Pushpalatha, S.,
Arularasu, M. V., Palanivel, C., Rajendran, T. V., & Manikandan, A. 2024,
Green synthesis of cellulose/ZrO2 nanocomposite: assessment of antibacterial
and photocatalytic activity. Biomass
Conversion and Biorefinery, 1–8.
[5].
Tang, X., Li, H., Zhang,
T., Zhong, J., & Du, H. 2022, P123-assisted hydrothermal synthesis of
Ag2MoO4 with enhanced photocatalytic performance. Inorganic Chemistry Communications, 141, 109613.
[6].
Appiagyei, A. B.,
Asiedua-Ahenkorah, L., Bathula, C., Kim, H. S., Han, S. S., Rao, K. M., &
Anang, D. A. 2023, Rational design of sucrose-derived graphitic carbon coated
MnMoO4 for high performance asymmetric supercapacitor. Journal of Energy Storage, 58, 106383.
[7].
Tourchi Moghadam, M. T.,
Seifi, M., Jamali, F., Azizi, S., & Askari, M. B. 2022, ZnWO4-CNT as a
superior electrode material for ultra-high capacitance supercapacitor. Surfaces and Interfaces, 32, 102134.
[8].
Sousa, G. da S., Nobre,
F. X., Araújo Júnior, E. A., Sambrano, J. R., Albuquerque, A. dos R., Bindá, R.
dos S., … de Matos, J. M. E. 2020, Hydrothermal synthesis, structural
characterization and photocatalytic properties of β-Ag2MoO4 microcrystals:
Correlation between experimental and theoretical data. Arabian Journal of Chemistry, 13(1), 2806–2825.
[9].
Mispa, K. J.,
Subramaniam, P., & Murugesan, R. 2014, Studies on polyaniline/silver
molybdate nanocomposites. International
Journal of Nanoscience, 13(1),
1050002.
[10]. Safartoobi, A., Mazloom, J., & Ghodsi, F. E. 2023,
Silver/molybdenum metal-organic framework derived Ag2MoO4 nanoparticles as
novel electrode for high-performance supercapacitor. Journal of Energy Storage, 68, 107818.
[11]. Jayanthi, P., Duraimurugan, J., Prabhu, S., Siranjeevi, R., Mary Anjalin, F.,
and Bhuvaneswari, N. 2024, Enhanced electrochemical performance of CoMoO4/r-GO
composites as electrode material for supercapacitor application. Diamond and Related Materials, 148, 111361.
[12]. Maity, S., Bain, D., Chakraborty, S., Kolay, S., & Patra,
A. 2020, Copper Nanocluster (Cu23NC)-Based Biomimetic System with Peroxidase
Activity. ACS Sustainable Chemistry
and Engineering, 8(49),
18335-18344.
[13]. Wang, N., Han, Z., Fan, H., & Ai, S. 2015, Copper
nanoparticles modified graphitic carbon nitride nanosheets as a peroxidase
mimetic for glucose detection. RSC
Advances, 5(111),
91302–91307.
[14]. Fabbro, M. T., Saliby, C., Rios, L. R., La Porta, F. A.,
Gracia, L., Li, M. S., … Longo, E. 2015, Identifying and rationalizing the
morphological, structural, and optical properties of β-Ag2MoO4 microcrystals,
and the formation process of Ag nanoparticles on their surfaces: Combining
experimental data and first-principles calculations. Science and Technology of Advanced Materials, 16(6).
[15]. Malathi, A., Priyadharsan, A., Handayani, M., Hasan, I.,
Divya, G., Sivaranjani, K., & Sivakumar, S. 2024, Boosted solar-driven
photocatalysis: silver molybdate/reduced graphene oxide nanocomposites for
methylene blue decomposition. Ionics,
30(3), 1603-1614.
[16]. Senthil, R. A., Wu, Y., Liu, X., & Pan, J. 2021, A facile
synthesis of nano AgBr attached potato-like Ag2MoO4 composite as highly
visible-light active photocatalyst for purification of industrial waste-water. Environmental Pollution, 269, 116034.
[17]. Syed, A., AL-Shwaiman, H. A., Al Khulaifi, M. M., Al Zahrani,
R. R., Almajhdi, F. N., & Elgorban, A. M. 2021, Integrating plasmonic
effect and nano-heterojunction formation for boosted light harvesting and
photocatalytic performance using CaWO4/Ag2MoO4 and its antibacterial
applications. Materials Science in
Semiconductor Processing, 133,
105921.
[18]. Balasurya, S., Okla, M. K., AL-ghamdi, A. A., Al-amri, S. A.,
Alatar, A. A., Abdel-Maksoud, M. A., … Khan, S. S. 2023, CaMoO4 modified
nanorods-branched Ag2MoO4 a nano-diatomic heterojunction as efficient
visible-light-driven photocatalysts for water remediation processes and
antimicrobial applications. Materials
Today Communications, 34,
104945.
[19]. Lopes, F. H. P., Noleto, L. F. G., Vieira, V. E. M., de
Sousa, P. B., Jucá, A. C. S., Oliveira, Y. L., … Cavalcante, L. S. 2023,
Experimental and Theoretical Correlation of Modulated Architectures of
β-Ag2MoO4 Microcrystals: Effect of Different Synthesis Routes on the
Morphology, Optical, Colorimetric, and Photocatalytic Properties. Journal of Inorganic and Organometallic
Polymers and Materials, 33(2),
424–450.
[20]. Nandi, I., Chall, S., Chowdhury, S., Mitra, T., Roy, S. S.,
& Chattopadhyay, K. 2018, Protein Fibril-Templated Biomimetic Synthesis of
Highly Fluorescent Gold Nanoclusters and Their Applications in Cysteine
Sensing. ACS Omega, 3(7), 7703–7714.
[21]. Saylan, Y., Erdem, Ö., Inci, F., & Denizli, A. 2020,
Advances in biomimetic systems for molecular recognition and biosensing. Biomimetics. 5(2), 20.
